Investigation of intermixing in TiAlN/VN nanoscale multilayer coatings by energy-filtered TEM

Meidia, Hira and Cullis, Anthony G. and Schönjahn, Cornelia and Münz, Wolf Dieter and Rodenburg, John Marius (2002) Investigation of intermixing in TiAlN/VN nanoscale multilayer coatings by energy-filtered TEM. Surface and Coatings Technology, 151. pp. 209-213. ISSN 0257-8972

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Abstract

We employ high-resolution energy-filtered cross-sectional transmission electron microscopy (EFTEM) to estimate the degree of layer intermixing in a TiAlN/VN low friction, wear-resistant nanoscale multilayers with a periodicity of approximately 4 nm grown by industrial-scale unbalanced magnetron ion-assisted PVD. Coatings are examined by high-resolution TEM imaging. A series of high-resolution elemental distribution maps are obtained by tuning the electron energy-loss imaging filter to the core loss energies of the elements present. We compare the experimental composition profiles with calculations, which model intermixing at the interface of the layers by a convolution. Although no physical shutter is employed in the industrial process (the substrate is passed in front of alternating targets in a confined plasma), the resulting layers are well differentiated.

Item Type: Article
Keywords: PVD; TiAlN/VN; Superlattice; Intermixing; EELS
Subjects: 500 Science and Mathematic > 530 Physics
Divisions: Faculty of Engineering & Informatics > Computer Engineering
Depositing User: Administrator UMN Library
Date Deposited: 06 Dec 2021 14:15
Last Modified: 27 Jan 2022 03:28
URI: https://kc.umn.ac.id/id/eprint/19362

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